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Whenever an item needs to be made light weight and high strength, titanium is always considered for its manufacture. Most titanium alloys possess the same strength as common grades of stainless steel, but are 40% less dense (the weight per volume area). Titanium therefore is commonly chosen for the manufacture of aircraft parts and medical equipment where strength at a lightweight is important.
In a wood head, even though a driver head, for example, will always be designed to weigh between 190g – 205g, the lower density of titanium allows the head to be made much larger in size and still possess the same strength than if a steel alloy were used. Steel's higher density means the maximum size for a wood head is about 310-320cc before the head would exceed the weight requirement for a normal club. Titanium driver heads can be made larger than 500cc and still weigh 190g – 200g because of the lower density.
In addition, titanium possesses a higher strength to modulus ratio than steel. This means it is possible to manufacture the face of a wood head from titanium and achieve a better spring face performance (high COR) than with all but extremely high strength steel alloys.
Metallurgy has developed hundreds of different tests to compare the mechanical properties of metals to each other. In golf, for the manufacture of club heads, there are four key metal mechanical properties in the production of titanium wood heads. A titanium wood head is constructed of 3 to 4 pieces welded together. Each different piece (face, crown, skirt, sole) has different stress put on it and is looked to perform different duties, therefore each piece can be made of differing titanium alloys. The mechanical properties needed to produce a high COR face are not the same as the crown.
The key properties of Titanium for wood head design are: Density The ratio of the mass of a substance to its
volume, expressed, for example, in units of grams per cubic centimeter or
pounds per cubic foot. The density of a pure substance varies little from
sample to sample and is often considered a characteristic property of the
substance. Density often is taken as an indication of how "heavy" a
substance is. Iron is denser than cork, since a given volume of iron is more
massive (and weighs more) than the same volume of cork. It is often said
that iron is "heavier" than cork, although a large volume of cork obviously
can be more massive and thus be heavier (i.e., weigh more) than a small
volume of iron. This is a property that is very important in all parts
of the club head as we like as light, low density, a club head as possible.
Tensile Strength The
measure of a material's ability to resist rupture. In other words, how much
force is required to fracture the material. Tensile strength is also defined
in PSI or KSI. This too is also important for the manufacture of the face
and body parts of a wood head. Hardness A comparative scale measurement of the
ability of a material to resist surface deformation. In other words, how
much does one material resist permanent denting of its surface. While there
are several scales of comparison for hardness, the one most commonly used in
conjunction with golf club head design is the Rockwell Scale of Hardness.
Hardness is important for all parts of a wood head, though more important for
the face. Elongation A comparison of the ductility of
different materials. In other words, how easy is one material to stretch
than another before it breaks such that the higher the number the easier to
stretch the material before breaking. Elongation is defined as a per-cent of
the dimension of the test piece, such that a higher per-cent value
represents greater ductility of the material. Elongation is an important
property for both the face and the body parts of the wood head because it
will offer an indication of the ability of the face or top crown to flex
before permanent damage could occur. Titanium is a metallic element which in its pure form, possesses very low
strength and would be quite unsuitable for the moderate to high stress
requirements of the parts of a wood head. While some grades of pure titanium
(referred to as commercially pure (CP grades) are used in the
manufacture of the crown, sole and skirt parts of a wood head, most of the
Titanium materials known by clubmakers are titanium alloys. An alloy is a
metal that is a combination of different chemical elements mixed with the
base metal for the purpose of intentionally creating different but very
specific mechanical properties. Thus, titanium metals known to clubmakers by
names such as 6-4, 10-2-3, SP700, etc are all titanium alloys. One of the most confusing parts of evaluating the quality of a titanium wood head concerns the various grades and alloys used in their manufacture.
It is very common for 2 or 3 different grades or alloys of titanium to be
used in the manufacture of the various parts of the head. The names or
numerical designations of the various titanium alloys are commonly used in
the marketing of the heads to try to associate levels of quality with one
specific Ti alloy over another. Is a 10-2-3 titanium alloy better than an
SP700? Does 22-4 titanium allow a wood head to perform better than 15-3-3-3
titanium? Why are different alloys of titanium used in the manufacture of a wood head? Because companies that sell
titanium wood heads do attempt to make
performance oriented claims with regard to the various alloys, questions
like this swim around in the minds of clubmakers and more technically
oriented golfers. The truth? For one, no single titanium material on its own makes a better
performing club head. There are titanium alloys that afford the potential
to make a better performing wood head, but how that alloy is used and how its
final properties are controlled in the manufacture of the wood head are the
real points about whether a specific titanium material has any bearing on
the performance of the head.
10-2-3 Beta Titanium. 6-4 Alpha/Beta Titanium. 15-3-3-3 Beta Titanium.
SP700 Beta Titanium. DAT51 Titanium. CP Grade Titanium. The names
of the different alloys and grades of titanium go on and on and each one supposedly
different in its performance when used in the making of a wood head. The most common method of naming Titanium alloys involves the use of a
hyphenated numbering system that identifies the chief chemical element
properties of the material. Present in addition to these important elements
that set each alloy apart from the next are trace amounts of Carbon,
Nitrogen, Oxygen, to name a few, with of course the balance of the alloy
being titanium itself. A number of examples that use the numerical system to
denote chemical composition of the alloy that are common to wood head
manufacture are listed as follows: Clubmakers have also heard of titanium alloy and material names such as
SP700, DAT51, CP grade that do not use this hyphenated number system. Such
designations are usually created by companies in foreign countries that do
not choose to subscribe to the hyphenated number system. For example, SP700
and DAT51 are titanium alloys made by Japanese companies and represent a
'trade name' for the alloy created by the company that makes the alloy. The
same practice occurs in the US, where companies who process the alloys
sometimes choose a trade name for the alloy instead of choosing to label the
material by a numerical designation of its chief chemical components.
Because all alloys are a combination of different amounts of different
metallic elements, every Titanium alloy can be expressed by a chemical
designation as well. But for purposes of this discussion, when a titanium
alloy is identified by a designation other than a hyphenated series of
numbers, that designation is a trade name for the alloy. For example, SP700 Titanium, which is an alpha/beta grade alloy (not a
beta grade like some companies advertise), could also referred to as
4.5-3-2-2 Titanium (4.5% Aluminum, 3% Vanadium, 2% Molybdenum, 2% Iron).
Same for DAT51, a trade name created by Kobe Steel of Japan for their
version of a 22-4 Titanium alloy.
Titanium’s 15-3-3-3 and SP700 offer tradeoffs when considering which may be
better to seek when making your next purchase. 15-3-3-3 has the highest tensile
strength of the 2 but a smaller elongation percentage. Meanwhile, SP700 still
possesses considerable tensile strength but does add a few percentage points in
the category of elongation. How does this translate? SP700, through its’ higher
elongation figure, can impart more spring upon impact, and thus deliver more
energy to the golf ball increasing distance. 10-2-3, SP700 and 22-4/DAT51 Titanium all have a very good
balance of high strength to low modulus and therefore are very good to use
to make Driver faces. 15-3-3-3 if process properly is very good as well,
although there is a little more tendency for 15-3-3-3 to become brittle than
the others mentioned here. 6-4 Titanium has the best elasticity of any
titanium used in club head design, but its strength is much lower than
10-2-3/SP700/22-4/DAT51 so it is better for use in fairway woods with
smaller faces, or for Drivers designed for much slower swing speed players. 6-4 Titanium
Titanium is used in wood heads
manufactured with the formula 6Al-4V: these are 90% Titanium, 6% Aluminum and 4%
Vanadium. Titanium is often used in oversize and larger heads. This alloy of
titanium is primarily used in the construction of the shell the head is
constructed of and not the face. Unless stated specifically titanium heads
advertised as Beta-Titanium use this alloy(6-4 Titanium) for the shell of the
head and Beta-Titanium(15-3-3-3 Beta-Ti) in the face. Mechanical Properties VS REAL Mechanical Properties of Titanium
Metals can be subjected to a process of precise heating over specific
amounts of time to ordain the FINAL REAL mechanical properties of the metal
in the specific part being made. While the science of heat treatment or
post-forming treatment is very detailed, in short, the post-forming
treatment of the metal is intended to cause the molecular structure of the
metal to be changed in specific and predictable ways to achieve a variety of
final mechanical and structural properties that may be more desired for the
performance of the part. For example, depending on the heat treatment followed, the tensile
strength of 6-4 Titanium will range from 120,000 psi up to 170,000!! Or as
another example, depending on the heat treatment process, 10-2-3 beta
Titanium will range in tensile strength from 135,000 psi to 210,000 psi!
Most clubmakers assume that 10-2-3 Beta Titanium will always have a much
higher strength than 6-4 Titanium. This is not true unless you know the
post-forming heat treatment process used. The same is true for all of the
Titanium alloys used in the manufacture of wood heads. Therefore, it is
IMPOSSIBLE without knowing the heat treatment procedure to know what any
mechanical property of any Titanium alloy will be in the end product. As a
result, heat treatment or post-forming treatment procedures are a CRITICAL
part of the designer's and the foundry's responsibility to ensure the
performance of the wood head's parts are properly created. Heat Treatment of a Titanium wood head will affect each and every
mechanical property in addition to the one example mentioned in the previous
paragraph. Because each of the properties plays its own important role in
the manufacture and ultimate performance of a Titanium wood head, a high
quality head not only requires a good design but excellent control on the
processing of the materials used in its creation. This is one reason
you can see the price of titanium club heads constructed of the same alloys
vary considerably. Heat treating is as much or more important than
using a specific titanium alloy.
IN GOLF INC.
So what are the trade off’s? Cost. Though this figure
varies widely, the SP700 titanium is typically a bit more expensive than the
15-3-3-3, usually on the order of $20 - $40. This amount is oftentimes minimized
by using SP700 strictly in the face of the driver head. Also, the higher one’s club head speed, the more realized benefit that could be realized from the
increased spring effect of SP700. Golfers with a lower swing speed may not
notice substantial yardage gains when comparing the two and therefore may not
wish to pay this premium. Truly though, it is hard to go wrong with using either
titanium as both offer such incredible playing characteristics, such vast
improvements over stainless steel
Ideally you would want to use the Beta Titanium alloy with 210,000 psi
strength AND 14 million psi Modulus of Elasticity. But the higher the
strength, the higher the modulus will be. Therefore, any Beta Titanium alloy
selected involves making a judgment of the balance of the two properties and
how that will translate into the performance of the finished face design of
the Driver.
Density (lb/in³)
Tensile Strength (psi)
Hardness
Elongation(%)
0.16
135,000
36 HRC
15
15-3-3-3 Forged Beta-Ti
Titanium is used in wood heads manufactured with
the formula 15V-3Sn-3Cr-3Al: these are 76% Titanium, 15% Vanadium, 3% Tin, 3%
Chromium and 3% Aluminum . Titanium is often used in oversize and larger heads
most importantly in face design.
Density (lb/in³)
Tensile Strength (psi)
Hardness
Elongation(%)
0.172
145,000
32 HRC
8
15-5-3
Titanium
Titanium Alloy used in head construction, not more than
75%
titanium, 15% Molybdenum,
5% Zirconium and 3% Aluminum. The most common used in high quality
woods. Harder than 17-4 stainless steel.
Density (lb/in³)
Tensile Strength (psi)
Hardness
Elongation(%)
0.181
181,000
35 HRC
5
10-2-3
Titanium
Titanium is used in wood heads manufactured with
the formula 10V-2Fe-3Al: these are 85% Titanium, 10% Vanadium and 3% Aluminum .
Titanium is often used in oversize and larger heads. Airplane black boxes
Density (lb/in³)
Tensile Strength (psi)
Hardness
Elongation(%)
0.168
180,000
41 HRC
6
SP700
Titanium
Titanium is used in wood heads manufactured with the formula 4.5Al-2.5Fe-2Mo-3V:
these are 88% Titanium, 4.5% Aluminum, 2.5% Iron, 2% Molybdenum and 3% Vanadium.
Titanium is often used in oversize and larger heads most importantly in face
design. Japanese grade
tested heat treated
Density (lb/in³)
Tensile Strength (psi)
Hardness
Elongation(%)
0.163
148,000
45 HRC
19
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